Thursday, October 27, 2022

Solid Waste Management: Causes, effects and control measures of urban and industrial waste

 

16 

Solid Waste Management: Causes, effects and control measures of urban and industrial waste

In ancient cities, food scraps and other wastes were simply thrown into the unpaved streets where they accumulated. Around 320 B.C. in Athens, the first known law forbidding this practice was established and a system of waste removal began to evolve in several eastern Mediterranean cities. Disposal methods were very crude and often were just open pits outside the city walls. As populations increased, efforts were made to transport the wastes out further thus creating city dumps. Until recently the disposal of municipal solid waste did not attract much public attention. The favoured means of disposal was to dump solid wastes outside the city or village limits.

Around most towns and cities in India the approach roads are littered with multi-coloured plastic bags and other garbage. Waste is also burnt to reduce its volume. Modern methods of disposal such as incineration and the development of sanitary landfills, etc. are now attempting to solve these problems. Lack of space for dumping solid waste has become a serious problem in several cities and towns all over the world. Dumping and burning wastes is not an acceptable practice today from either an environmental or a health perspective. Today disposal of solid waste should be part of an integrated waste management plan. The method of collection, processing, resource recovery and the final disposal should mesh with one another to achieve a common objective.

Characteristics of municipal solid waste

Solid wastes are grouped or classified in several different ways. These different classifications are necessary to address the complex challenges of solid waste management in an effective manner. The term municipal solid waste (MSW) is generally used to describe most of the non-hazardous solid waste from a city, town or village that requires routine collection and transport to a processing or disposal site. Sources of MSW include private homes, commercial establishments and institutions as well as industrial facilities. However, MSW does not include wastes from industrial processes, construction and demolition debris, sewage sludge, mining wastes or agricultural wastes.

Municipal solid waste contains a wide variety of materials. It can contain food waste such as vegetable and meat material, left over food, egg shells, etc which is classified as wet garbage as well as paper, plastic, tetrapacks, plastic cans, newspaper, glass bottles, cardboard boxes, aluminum foil, metal items, wood pieces, etc. which is classified as dry garbage.

Control measures of urban and industrial wastes

 An integrated waste management strategy includes three main components: 1. Source reduction 2. Recycling 3. Disposal

Source reduction is one of the fundamental ways to reduce waste. This can be done by using less material when making a product, reuse of products on site, designing products or packaging to reduce their quantity. On an individual level we can reduce the use of unnecessary items while shopping, buy items with minimal packaging, avoid buying disposable items and also avoid asking for plastic carry bags.

Recycling is reusing some components of the waste that may have some economic value. Recycling has readily visible benefits such as conservation of resources reduction in energy used during manufacture and reducing pollution levels. Some materials such as aluminum and steel can be recycled many times. Metal, paper, glass and plastics are recyclable. Mining of new aluminum is expensive and hence recycled aluminum has a strong market and plays a significant role in the aluminum industry. Paper recycling can also help preserve forests as it takes about 17 trees to make one ton of paper. Crushed glass (cullet) reduces the energy required to manufacture new glass by 50 percent. Cullet lowers the temperature requirement of the glassmaking process thus conserving energy and reducing air pollution. However, even if recycling is a viable alternative, it presents several problems.

The problems associated with recycling are either technical or economical. Plastics are difficult to recycle because of the different types of polymer resins used in their production. Since each type has its own chemical makeup different plastics cannot be recycled together. Thus, separation of different plastics before recycling is necessary. Similarly in recycled paper the fibers are weakened and it is difficult to control the colour of the recycled product. Recycled paper is banned for use in food containers to prevent the possibility of contamination. It very often costs less to transport raw paper pulp than scrap paper. Collection, sorting and transport account for about 90 per cent of the cost of paper recycling. The processes of pulping, deinking and screening wastepaper are generally more expensive than making paper from virgin wood or cellulose fibers. Very often thus recycled paper is more expensive than virgin paper. However as technology improves the cost will come down.

Disposal of solid waste is done most commonly through a sanitary landfill or through incineration. A modern sanitary landfill is a depression in an impermeable soil layer that is lined with an impermeable membrane. The three key characteristics of a municipal sanitary landfill that distinguish it from an open dump are:

• Solid waste is placed in a suitably selected and prepared landfill site in a carefully prescribed manner.

• The waste material is spread out and compacted with appropriate heavy machinery.

• The waste is covered each day with a layer of compacted soil.

The problem with older landfills are associated with groundwater pollution. Pollutants seeping out from the bottom of a sanitary landfill (leachates) very often percolate down to the groundwater aquifer no matter how thick the underlying soil layer. Today, it is essential to have suitable bottom liners and leachate collection systems along with the installation of monitoring systems to detect groundwater pollution. The organic material in the buried solid waste will decompose due to the action of microorganisms. At first the waste decomposes aerobically until the oxygen that was present in the freshly placed fill is used up by the aerobic microorganisms. The anerobes take over producing methane which is poisonous and highly explosive when mixed with air in concentrations between 5 and 15 per cent. The movement of gas can be controlled by providing impermeable barriers in the landfill. A venting system to collect the blocked gas and vent it to the surface where it can be safely diluted and dispersed into the atmosphere is thus a necessary component of the design of sanitary landfills.

Even though landfilling is an economic alternative for solid waste disposal, it has become increasingly difficult to find suitable landfilling sites that are within economic hauling distance and very often citizens do not want landfills in their vicinity. Another reason is that no matter how well engineered the design and operation may be, there is always the danger of some environmental damage in the form of leakage of leachates.

Incineration is the process of burning municipal solid waste in a properly designed furnace under suitable temperature and operating conditions. Incineration is a chemical process in which the combustible portion of the waste is combined with oxygen forming carbon dioxide and water, which are released into the atmosphere. This chemical reaction called oxidation results in the release of heat. For complete oxidation the waste must be mixed with appropriate volumes of air at a temperature of about more than 850o C for minimum of 2 seconds or 815 OC about one hour. Incineration can reduce the municipal solid waste by about 90 per cent in volume and 75 per cent in weight. The risks of incineration however involve air quality problems and toxicity and disposal of the fly and bottom ash produced during the incineration process. Fly ash consists of finely divided particulate matter, including cinders, mineral dust and soot. Most of the incinerator ash is bottom ash while the remainder is fly ash. The possible presence of heavy metals in incinerator ash can be harmful. Thus toxic products and materials containing heavy metals (for example batteries and plastics) should be segregated. Thus extensive air pollution control equipment and high-level technical supervision and skilled employees for proper operation and maintenance is required. Thus while sanitary landfills and incinerators have their own advantages and disadvantages, the most effective method of solid waste management is source reduction and recycling.

Vermi – Composting

Nature has perfect solutions for managing the waste it creates, if left undisturbed. The biogeochemical cycles are designed to clear the waste material produced by animals and plants. We can mimic the same methods that are present in nature. All dead and dry leaves and twigs decompose and are broken down by organisms such as worms and insects, and is finally broken down by bacteria and fungi, to form a dark rich soil-like material called compost.

These organisms in the soil use the organic material as food, which provides them with nutrients for their growth and activities. These nutrients are returned to the soil to be used again by trees and other plants. This process recycles nutrients in nature. This soil can be used as a manure for farms and gardens.

Steps for Vermi-Compost

• Dig a pit about half a meter square, one meter deep.

• Line it with straw or dried leaves and grass.

• Organize the disposal of organic waste into the pit as and when generated.

•The earth worms are sensitive to heat, hence any undecomposed material that produces heat should be avoided. The heat genetration can be reduced by a process called the process called pre-composting. Introduce a culture of worms that is now produced commercially.

• Ensure that the contents are covered with a sprinkling of dried leaves and soil everyday.

• Water the pit once or twice a week to keep it moist.

• Turn over the contents of the pit ever 15 days.

• In about 45 days the waste will be decomposed by the action of the microorganisms.

• The soil derived is fertile and rich in nutrients.

Hazardous wastes

Modern society produces large quantities of hazardous waste which are generated by chemical manufacturing companies, petroleum refineries, paper mills, smelters and other industries. Hazardous wastes are those that can cause harm to humans or the environment. Wastes are normally classified as hazardous waste when they cause or significantly contribute to an increase in mortality or an increase in serious irreversible or incapacitating reversible illness or pose a substantial present or potential hazard to human health or the environment when improperly treated, stored, transported or disposed of.

Characteristics of hazardous wastes

A waste is classified as a hazardous waste if it exhibits any of the four primary characteristics based on the physical or chemical properties of toxicity, reactivity, ignitability and corrosivity. In addition to this waste products that are either infectious or radioactive are also classified as hazardous

Toxic wastes are those substances that are poisonous even in very small or trace amounts. Some may have an acute or immediate effect on humans or animals causing death or violent illness. Others may have a chronic or long term effect slowly causing irreparable harm to exposed persons. Acute toxicity is readily apparent because organisms respond to the toxin shortly after being exposed. Chronic toxicity is much more difficult to determine because the effects may not be seen for years. Certain toxic wastes are known to be carcinogenic, causing cancer and others may be mutagenic causing biological changes in the children of exposed people and animals.

Reactive wastes are those that have a tendency to react vigorously with air or water, are unstable to shock or heat, generate toxic gases or explode during routine management. For example, gunpowder, nitroglycerine, etc.

Ignitable wastes are those that burn at relatively low temperatures (less than 60 C) and are capable of spontaneous combustion during storage, transport or disposal. For example, gasoline, paint thinners, and alcohol.

Corrosive wastes are those that destroy materials and living tissue by chemical reaction. For example, acids and bases.

Infectious wastes include human tissue from surgery, used bandages and hypodermic needles, microbiological materials, etc.

Radioactive waste is basically an output from the nuclear power plants and can persist in the environment for thousands of years before it decays appreciably.

Environmental problems and health risks caused by hazardous wastes

As most of the hazardous wastes are disposed of on or in land the most serious environmental effect is contaminated groundwater. Once groundwater is polluted with hazardous wastes it is very often not possible to reverse the damage.

Pesticides are used increasingly to protect and increase food production. They form residues in the soil which are washed into streams which then carry them forwards. The residues may persist in the soil or in the bottom of lakes and rivers. Exposure can occur through ingestion, inhalation and skin contact resulting in acute or chronic poisoning. Today we have an alternative to the excess use of pesticides through the use of Integrated Pest Management (IPM). The IPM system uses a wide variety of plants and insects to create a more natural process. The natural balance between climate, soil and insect populations can help to prevent an insect from overpopulating an area and destroying a particular crop.

Lead, mercury and arsenic are hazardous substances which are often referred to as heavy metals. Lead is an abundant heavy metal and is relatively easy to obtain. It is used in batteries, fuel, pesticides, paints, pipes and other places where resistance to corrosion is required. Most of the lead taken up by people and wildlife is stored in bones. Lead can affect red blood cells by reducing their ability to carry oxygen and shortening their life span. Lead may also damage nerve tissue which can result in brain disease.

Mercury occurs in several different forms. Mercury is used in the production of chlorine. It is also used as a catalyst in the production of some plastics. Industrial processes such as the production of chlorine and plastics are responsible for most of the environmental damage resulting from mercury. Our body has a limited ability to eliminate mercury. In the food web mercury becomes more concentrated as it is taken up by various organisms. In an aquatic environment, mercury can be absorbed by the plankton which are then consumed by fish. In addition, fish take up mercury through their gills and by eating other fish contaminated with mercury. Generally older the fish greater is the mercury concentration in its body. Birds that eat the fish concentrate even more mercury in their bodies. It is a cumulative poison (it builds up in the body over long periods of time) and is known to cause brain damage.

Thousands of chemicals are used in industry everyday. When used incorrectly or inappropriately they can become health hazards. PCBs (Polychlorinated biphenyls) are resistant to fire and do not conduct electricity very well which makes them excellent materials for several industrial purposes. Rainwater can wash PCBs out of disposal areas in dumps and landfills thus contaminating water. PCBs do not break down very rapidly in the environment and thus retain their toxic characteristics. They cause long term exposure problems to both humans and wildlife. PCBs are concentrated in the kidneys and liver and thus cause damage. They cause reproductive failure in birds and mammals.

Vinyl chloride is a chemical that is widely used in the manufacture of plastic. Usually people are only exposed to high levels of vinyl chloride if they work with it or near it but exposure can also occur from vinyl chloride gas leaks. After a long continuous exposure (one to three years) in humans, vinyl chloride can cause deafness, vision problems, circulation disorders and bone deformities. Vinyl chloride can also cause birth defects.

It is essential to substitute the use of PCBs and vinyl chloride with chemicals that are less toxic. Polyvinyl chloride use can be lowered by reducing our use of plastics. Thus by reducing waste, encouraging recycling and using products that are well made and durable we can greatly reduce our consumption of these chemicals thus curtailing our exposure to these substances.

We may not realize it but many household chemicals can be quite toxic to humans as well as wildlife. Most of the dangerous substances in our homes are found in various kinds of cleaners, solvents and products used in automotive care. When these products are used incorrectly they have the potential to be harmful.

Today the most common methods for disposing off hazardous wastes are land disposal and incineration. In countries where there is abundant land available for disposal for example, North America land disposal is the most widely used method. In countries like Europe and Japan where land is not readily available and is expensive, incineration is the preferred method for disposal. In spite of strong laws however illegal dumping of these wastes continues. Hazardous waste management must move beyond burying and burning. Industries need to be encouraged to generate less hazardous waste in their manufacturing processes. Although toxic wastes cannot be entirely eliminated, technologies are available for minimizing, recycling and treating wastes. An informed public can also contribute in a big way towards this end. It is essential for us to understand the ill effects of chemical substances so that we can make informed decisions about its use. We might decide that the benefits of the use of a toxic substance do not outweigh the risks and choose not to use it at all or we may decide that it is acceptable to use a substance under certain specific circumstances where it is adequately controlled and exposure to toxic levels is prevented.

Minamata-An important lesson about mercury

A case of human mercury poisoning which occurred about forty years ago in the Minamata bay in Japan taught the world an important lesson about the dangers of mercury poisoning. A large plastics plant located near the Minamata bay used a mercury containing compound in a reaction to produce vinyl chloride a common plastic material. The left over mercury was dumped into the Bay along with other wastes from the plant. Though the mercury was in its less toxic inorganic state when dumped microorganisms at the bottom of the bay converted the mercury into its organic form. This organic mercury then entered into the tissues of fish which were in turn consumed by the people living in the area. The contaminated fish thus caused an outbreak of poisoning killing and affecting several people. Mothers who had eaten the contaminated fish gave birth to infants who showed signs of mercury poisoning. Mercury poisoning is thus called Minamata Disease.

No comments:

Post a Comment